Preparation of Sm3+–Eu3+ coactivating red-emitting phosphors and improvement of their luminescent properties by charge compensation |
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| Authors: | F-b Cao Y-j Chen Y-w Tian L-j Xiao L-k Li |
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| Institution: | 1. School of Materials and Metallurgy, Northeastern University, Shenyang, 110004, People’s Republic of China
2. Shenyang Institute of Chemical Technology, Shenyang, 110142, People’s Republic of China
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| Abstract: | By charge compensating, a series of red-emitting phosphors Ca0.54Sr0.16Ca0.54Sr0.31Eu0.08Sm0.02(MoO4)0.6(WO4)0.4 were synthesized. Two approaches to charge compensation were used: (a) 2Ca2+/Sr2+→Eu 3+/Sm3++M +, where M+ is a monovalent cation like Li+, Na+ or K+; (b) Ca2+/Sr2+→Eu 3+/Sm3++N ?, where N+ is a monovalent anion like F?, Cl?, Br?, or I?. One red LED was made by combining the phosphor and 390–405 nm emitting LED chip under 20 mA forward-bias current, the color purity, chromaticity coordinates and the luminous intensity of which were 99.5%, x=0.66, y=0.33, 5600 mcd, respectively. |
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