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Solid state reactions of nitrogenous heterocyclic compounds(Ⅰ)——Solid state reactions of 3-methyl-l-phenyl-5-pyrazolone with carbonyl compounds
引用本文:李晓陆,杜大明,王永梅,孟继本.Solid state reactions of nitrogenous heterocyclic compounds(Ⅰ)——Solid state reactions of 3-methyl-l-phenyl-5-pyrazolone with carbonyl compounds[J].中国科学B辑(英文版),1997(2).
作者姓名:李晓陆  杜大明  王永梅  孟继本
作者单位:Department of Chemistry,Nankai University,Tianjin 300071,China,Department of Chemistry,Nankai University,Tianjin 300071,China,Department of Chemistry,Nankai University,Tianjin 300071,China,Department of Chemistry,Nankai University,Tianjin 300071,China
基金项目:Project supported by the National Natural Science Foundation of China
摘    要:The solid state reaction of 3-methyl-1-phenyl-5-pyrazolone (MPP) with aromatic aldehydes and ke-tones benzil derivatives and imides,and the solid state Michael addition reaction of MPP with 4-arylidene-3-methyl-1-phenyl-5-pyrnzolone 2 were investigated.Some new solid state reactions between the reactants were found,from which a series of new compounds were obtained The structures of the products were identified by IR,1H NMR,MS,elemental analyses and also by X-ray crystal analysis,and the reaction mechanism of MPP with aromatic aldehydes and ketones was proposed

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