Existence of doubly charged lead monohydrate: experimental evidence and theoretical examination |
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| Authors: | Shi Tujin Orlova Galina Guo Jingzhong Bohme Diethard K Hopkinson Alan C Siu K W Michael |
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| Affiliation: | Department of Chemistry and Centre for Research in Mass Spectrometry, York University, Toronto, Ontario, Canada M3J 1P3. |
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| Abstract: | Despite reports to the contrary, doubly charged lead monohydrate is a stable species against both proton and charge transfers. [Pb(H(2)O)](2+) has been observed as a minor product in the ligand-exchange reaction of [Pb(CH(3)CN)](2+) with H(2)O after collisional activation. Density functional theory has been used to examine reaction profiles of [Pb(H(2)O)(n)](2+) where n = 1, 2, and 3. |
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