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醋酸十二铵的吸附和SiO2悬浮液的稳定性
引用本文:钱建刚,顾惕人. 醋酸十二铵的吸附和SiO2悬浮液的稳定性[J]. 物理化学学报, 1996, 12(8): 698-703. DOI: 10.3866/PKU.WHXB19960806
作者姓名:钱建刚  顾惕人
作者单位:Laboratory of Chemistry,Beijing University of Aeronautics and Astronautics,Beijing 100083
摘    要:(1)测定了醋酸十二烷基铵(DAA)在CAB-O-SIL上的吸附,其等温线属双平台或LS型[1-3,5];(2)NaCl的存在使DAA的吸附增加.但不影响其低浓度下第一平台的吸附量;HCl的存在则在全浓度范围内抑制了DAA的吸附,(3)测定了CAB-O-SIL颗粒在上述各溶液中的悬浮液的稳定性;(4)根据表面形成小胶团的吸附理论(即二步模型产)[2,3,5,],并借助电导跟踪溶液中发生的变化,满意地解释了吸附和聚沉的实验结果.

关 键 词:醋酸十二烷基铵  吸附  表面胶团化  二氧化硅  聚沉  悬浮液稳定性  
收稿时间:1996-01-15
修稿时间:1996-03-26

Effects of Adsorption and Surface Micellization of Dodecylammonium Acetate on the Stability of Silica Suspension
Qian Jiangang, Gu Tiren. Effects of Adsorption and Surface Micellization of Dodecylammonium Acetate on the Stability of Silica Suspension[J]. Acta Physico-Chimica Sinica, 1996, 12(8): 698-703. DOI: 10.3866/PKU.WHXB19960806
Authors:Qian Jiangang   Gu Tiren
Affiliation:Laboratory of Chemistry,Beijing University of Aeronautics and Astronautics,Beijing 100083
Abstract:(1) The adsorption of dodecylammonium acetate (DAA) on CAB-O-SIL has been investigated, the adsorption isotherm of DAA shows two plateaus (i.e. LS-type).(2) The addition of sodium chloridc increases the adsorption of DAA, but no significant change can be found in the first plateau at low concentrations; while the addition of hydrochloricacid decreases the adsorption of DAA in the experimental concentration region. (3) The stability of CAB-O-SIL suspension has been determined for the corresponding solutions.(4)Based on the two-step model of the surfactant adsorption theory proposed previously,and with the aid of conductivity measurements, the coagulation regularity of CAB-O-SILsuspension can be explained satisfactorily.
Keywords:Dodecylammonium acetate   Adsorption   Surface micellization   Silica  Coagulation   Stability of suspension
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