| CF3C(O)F水合作用的热力学和动力学理论研究 |
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| 引用本文： | 孙利鹏,马骜,王沂轩,刘成卜.CF3C(O)F水合作用的热力学和动力学理论研究[J].物理化学学报,1996,12(4):361-364. |
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| 作者姓名： | 孙利鹏 马骜 王沂轩 刘成卜 |
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| 作者单位： | College of Chemistry,Shandong University,Jinan 250100 |
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| 摘 要： | 由于氟氟烃（CFCs）对大气臭氧层有破坏作用，人们拟以另外的化合物来代替它，CF3CX2H（X＝H，CI，F）可能是一类合适的取代物．但人们对它及其反应产物对大气的影响还不清楚.CFaC（0）F是CFaCX。H大气光氧化过程的终产物之一1－3］，其在大气中的后继反应行为将直接关系到CF2
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| 关 键 词： | 热力学 动力学 CF3C(O)F 水合作用 |
| 收稿时间： | 1995-07-11 |
| 修稿时间： | 1995-09-11 |
Thermodynamic and Kinetic Study of Gas-phase Hydrolysis of CF_3C(O)F to CF_3COOH |
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| Sun Lipeng, Ma Ao, Wang Yixuan, Liu Chengbu.Thermodynamic and Kinetic Study of Gas-phase Hydrolysis of CF_3C(O)F to CF_3COOH[J].Acta Physico-Chimica Sinica,1996,12(4):361-364. |
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| Authors: | Sun Lipeng Ma Ao Wang Yixuan Liu Chengbu |
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| Institution: | College of Chemistry,Shandong University,Jinan 250100 |
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| Abstract: | Based on the ab initio calculated results, the thermodynamic functions and kinetic paramters of the gas-phase hydrolysis of CF3C(O)F to CF3COOH have been calculated in the temperature range 200-1500 K with statistical thermodynamic method and Eyring's transition state theory. The heat capacities of some important species ocurring in the reactions have been calculated and fitted in the formula (a bT cT2 dT3 eT4). |
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| Keywords: | Thermodynamics Kinetics CF_3C(O)F Gas-phase hydrolysis |
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