| Fe3(CO)8(C6H5NC)(μ3-S)2的合成和晶体结构 |
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| 引用本文： | 陆庆玮,王一兵,索全伶,吴宝山,孙杰.Fe3(CO)8(C6H5NC)(μ3-S)2的合成和晶体结构[J].物理化学学报,1996,12(6):532-536. |
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| 作者姓名： | 陆庆玮 王一兵 索全伶 吴宝山 孙杰 |
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| 作者单位： | Department of Chemical Engineering,Inner Mongolia Polytechnic Univeristy,Hohhot 010062,Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032 |
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| 摘 要： |
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| 关 键 词： | 合成 晶体结构 铁流簇合物 苯异腈基配体 |
| 收稿时间： | 1995-08-29 |
| 修稿时间： | 1996-01-22 |
Synthesis and Crystal Strucutre of Fe3(CO)8(C6H5NC)(μ3-S)2 |
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| Lu Qing-Wei,Wang Yi-Bing,Suo Quan-Ling,Wu Bao-Shan,Sun Jie.Synthesis and Crystal Strucutre of Fe3(CO)8(C6H5NC)(μ3-S)2[J].Acta Physico-Chimica Sinica,1996,12(6):532-536. |
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| Authors: | Lu Qing-Wei Wang Yi-Bing Suo Quan-Ling Wu Bao-Shan Sun Jie |
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| Institution: | Department of Chemical Engineering,Inner Mongolia Polytechnic Univeristy,Hohhot 010062|Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032 |
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| Abstract: | The title compound Fe_3(CO)_8(C_6H_5NC)(μ_3-S)_2 (Ⅰ) was synthesized by the reaction of C_6H_5NCS with Fe_3(CO)_12 at room temperature. The crystal and molecular structure of the title compound were determined by single ctystal diffraction method. Crystal data: monoclinic, space group P2_1/C, a=12.718(4)Å, b=26.164(10) Å, c=l3.741(7) Å, β=117.18(2) °, V=4067(2) Å3, Z=8, Dc=1.825 g/cm3. The structure was solved by direct method and difference Fourier synthesis, and refined by full-matrix Least-squares with anisotropic thermal paramaters, using 1990 observed reflections Ⅰ＞3σ(Ⅰ)].The final residual factor was R＝0.076, Rw＝0.082. The substituted ligand (C_6H_5NC)in Fe_3(CO)_8(C_6H_5NC)(μ_3-S)_2 is connected to the Fe(3) atom of the distorted tetragonal pyramid Fe_3S_2 framework. |
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| Keywords: | Synthesis Crystal structure Sulfuro-iron cluster Isocyanide derivative |
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