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Excitonic luminescence in oligothiophene aggregated films and self-assembled monolayers
Authors:E. Mishina   N. Sherstyuk   S. Semin   S. Nakabayashi  L. Kulyuk
Affiliation:aMoscow Institute of Radioengineering, Electronics and Automation, prosp. Vernadskogo 78, 117454 Moscow, Russia;bDepartment of Chemistry, Saitama University, Saitama, 338-8570, Japan;cInstitute of Applied Physics, Academy of Sciences, MD-2012 Chisinau, Republic of Moldova
Abstract:We studied the photoluminescence (PL) spectra of thiophene oligomers in a solution, and in a solid state: aggregated film and self-assembled monolayer (SAM). We showed a strong influence of packing conditions on the PL spectra. In the solid state a new electronic state was observed, which does not reveal itself in the solution.
Keywords:A. Thin films   A. Disordered systems   E. Luminescence   E. Light absorption and reflection
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