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Adsorption sites of CO on Pt (111)
Authors:H. Froitzheim  H. Hopster  H. Ibach  S. Lehwald
Affiliation:1. Institut für Grenzfl?chenforschung und Vakuumphysik, Kernforschungsanlage, D-5170, Jülich, Fed. Rep. Germany
Abstract:The surface vibrations of CO adsorbed on Pt(111) single crystal surfaces at 320 K have been studied by electron-energy-loss spectroscopy. At low coverages two vibration modes at 58 and ∼260 meV are observed. For exposures >0.2 Langmuir two additional modes at 45 and 232 meV develop. Considering also the observed LEED structures these vibrations are attributed to CO molecules being adsorbed upright in on-top and bridge sites, respectively.
Keywords:68.20
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