Stokes/anti-stokes intensity ratio in the resonance region |
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Authors: | Philip Joseph Miller Raj K Khanna |
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Institution: | Block Engineering, Inc., Cambridge, Massachusetts 02139, USA;Department of Chemistry, University of Maryland, College Park, Maryland 20742, USA |
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Abstract: | Relative intensities of the Stokes and anti-Stokes Raman lines associated with the I-I stretching mode of I2 and symmetric stretching mode of MnO?4 are presented. The data indicate that the maxima in the excitation profile of the anti-Stokes scattering are shifted from those of the Stokes scattering. The experimental Stokes/anti-Stokes intensity ratios agree with the theoretical values obtained with parameters from the electronic absorption spectra. |
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