Vibrational branching ratios for the A3Πi → X3Σ? system of OH+ and OD+ |
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| Authors: | M Gérard TR Govers CA Van De Runstraat R Marx |
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| Institution: | Laboratoire de Spectroscopie Hertzienne, associé au C.N.R.S., Université de Lille, 59650 Villeneuve D''Ascq, France |
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| Abstract: | Near-thermal charge exchange between He+ and H2(D2O) is used as a source of OH+(OD+) A3Hi→ X3Σ? emission. A comparison between experimental emission branching ratios and those calculated in the r-centroid approximation suggests that the electronic transition moment varies as a function of the r-centroid. |
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