Resonance raman and infrared spectra of ClO3 radicals in electron irradiated NaClO3 |
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Authors: | J.B. Bates H.D. Stidham |
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Affiliation: | Solid State Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830, USA |
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Abstract: | Resonance Raman and infrared absorption spectra of ClO3 radicals have been observed from measurements of crystalline NaClO3 irradiated at 77 K with 1.5 MeV electrons. The ClO3 radicals occupy two sets of nonequivalent sites; radicals at one site are observed from resonance scattering using 6328 Å excitation while those at the other site are observed from resonance scattering with 5145 Å excitation. The red sensitive radicals decompose at 77 K with a half-life of ≈29 min while the green sensitive radicals are more stable at this temperature. |
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