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Intramolecular excimer fluorescence,its solvent dependence,and photodimerization of 1,2-dianthrylethanes
Authors:Toyoharu Hayashi  Tatsuo Suzuki  Noboru Mataga  Yoshiteru Sakata  Soichi Misumi
Affiliation:Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka, Japan;Institute of Scientific and Industrial Research, Osaka University, Suita, Osaka, Japan
Abstract:Both 1,2-di(1-anthryl)ethane (I) and 1,2-di(9-anthryl) ethane (II) show two types of excimer fluorescence spectra under different conditions; one with peak at 460 nm (type-1) and the other with peak at 530 nm (type-2). Furthermore, the type-1 excimer emission shows a peculiar dependence upon the solvent polarity.
Keywords:To whom all correspondence should be addressed
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