Rate constants for the reaction of OH radicals with 2-methyl-2-butene over the temperature range 297–425 K |
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Authors: | R Atkinson RA Perry JN Pitts |
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Institution: | Department of Chemistry and Statewide Air Pollution Research Center, University of California, Riverside, California 92502, USA |
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Abstract: | Absolute rate constants, k2, for the reaction of OH radicals with 2-methyl-2-butene have been determined over the temperature range 297–425 K using a flash photolysis-resonance fluorescence technique. The Arrhenius expression obtained was k2 = 3.6 × 10?11 exp (450 ± 400)/RT] cm3 molecule?1 s?1. |
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