The X-ray photoelectron spectrum of sulphur vapour |
| |
| Authors: | M.S. Banna D.C. Frost C.A. McDowell B. Wallbank |
| |
| Affiliation: | Department of Chemistry, University of British Columbia, Vancouver, British Columbia, Canada V6T 1W5 |
| |
| Abstract: | The X-ray photoelectron spectrum of S8 vapour obtained with Al Kα radiation in a spectrometer designed for high temperature work is reported. The S2s and 2p levels were found to lie at 10.1(1) eV and 10.5(1) eV lower binding energy than the corresponding levels in SF6 and 0.5 eV lower than the levels in H2S. A S2p/S2s intensity ratio per electron of 0.40(3) was determined, in very good agreement with theory. The photoelectron spectrum in the molecular optical region was obtained and is in good agreement with a previously published spectrum of sulphur powder. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
