Relaxation of the optical Kerr effect of anisotropic molecules in mixed liquids |
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Authors: | P.P. Ho W. Yu R.R. Alfano |
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Affiliation: | Physics Department, The City College of the City University of New York, New York, New York 10031, USA |
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Abstract: | The relaxation time of the Kerr effect of nitrobenzene and m-nitrotoluene in various mixtures with carbon tetrachloride and various alcohols was determined by measuring the kinetics of the Kerr effect using picosecond laser techniques. These measurements yield information on the rotational motion of molecules in liquids. The relaxation time data are interpreted in terms of an effective local viscosity effect, pair correlation, and coupling of rotational motion with shear modes. |
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