Recombination of iodine atoms in an unsteady expansion |
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| Authors: | WH Beck JC Mackie |
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| Institution: | Department of Physical Chemistry, The University of Sydney, Sydney, N.S.W. 2006, Australia |
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| Abstract: | Recombination of iodine atoms generated by shock heating I2 in Ar is studied in an unsteady expansion. The three-body recombination rate coefficient has been measured as 3 × 1015 (T/298)?1.56 cm6 mol?2 s?1 between 500 and 1450 K. Coupling of vibrational and chemical relaxation is found to occur in the expansion. |
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