Vibrational energy transfer from the υ = 1 level of carbon monoxide to the υ = 1 level of the two isotopic species of nitrogen: 14N2 and 15N2 |
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Authors: | G Mastrocinque A Chakroun L Doyennette H Gueguen M Margottin-Maclou L Henry |
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Institution: | Laboratoire de Spectronomie Moléculaire, Université Pierre et Marie Curie, 75230 Paris Cedex 05, France |
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Abstract: | V-V transfer rates from CO (υ = 1) to 14N2 and 15N2 are determined from 100 to 700 K using the laser fluorescence method. The great effect of the energy level gap between the colliding partners is dramatically demonstrated. Theoretical considerations explain the observed difference. |
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