| Synthesis and Structural Characterization of Two Molybdenum~phosphate Cluster Compounds: (C_(14)N_(14)H_(63) )Na(H_2Mo_6P_4O_(31))_2·8H_2Oand(C_(14)N_(14)H_(63))Na(H_2Mo_6P_4O_(31) )_2·5H_2O |
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| 引用本文： | 温福山,陈伟,施展,李光华,于振涛,陈接胜. Synthesis and Structural Characterization of Two Molybdenum~phosphate Cluster Compounds: (C_(14)N_(14)H_(63) )Na(H_2Mo_6P_4O_(31))_2·8H_2Oand(C_(14)N_(14)H_(63))Na(H_2Mo_6P_4O_(31) )_2·5H_2O[J]. 中国化学, 2002, 20(9): 858-864. DOI: 10.1002/cjoc.20020200911 |
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| 作者姓名： | 温福山 陈伟 施展 李光华 于振涛 陈接胜 |
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| 作者单位： | WEN，Fu Shan CHEN，Wei SHI，Zhan LI，Guang Hua YU，Zhen Tao CHEN，Jie Sheng State Key Laboratory of Inorganic Synthesis and Preparative Chemistry，College of Chemistry，Jilin University，Changchun，Jilin 130023，China |
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| 基金项目： | theNationalNaturalScienceFoundationofChina (No.2 99310 10 )，theEducationMinistryofChina |
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| 摘 要： | ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｓｙｎｔｈｅｓｉｓａｎｄｓｏｒｐｔｉｏｎｐｒｏｐｅｒｔｉｅｓｏｆｏｐｅｎｆｒａｍｅ ｗｏｒｋｓｏｌｉｄｓｓｕｃｈａｓｚｅｏｌｉｔｅｓ1ａｎｄｍｅｔａｌｍｏｌｙｂｄｅｎｕｍｐｈｏｓ ｐｈａｔｅ2 ,3ｗｉｔｈｌａｒｇｅｃａｖｉｔｉｅｓｐｒｏｖｏｋｅｄｅｎｏｒｍｏｕｓｉｎｔｅｒｅｓｔｂｅ ｃａｕｓｅｏｆｔｈｅｉｒｐｏｔｅｎｔｉａｌａｐｐｌｉｃａｔｉｏｎｉｎｃａｔａｌｙｓｉｓ .Ｏｎｅ ,ｔｗｏ ａｎｄｔｈｒｅｅ ｄｉｍｅｎｓｉｏｎａｌｓｏｌｉｄｃｏｍｐｏｕｎｄｓｃｏｎｓｉｓｔｉｎｇｏ…
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Synthesis and Structural Characterization of Two Molybdenumphosphate Cluster Compounds: (C14N14H63) Na (H2Mo6P4O31)2 · 8H2O and (C14N14H63) Na (H2Mo6P4O31)2 · 5H2O |
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| Fu‐Shan Wen,Wei Chen,Zhan Shi,Guang‐Hua Li,Zhen‐Tao Yu,Jie‐Sheng Chen. Synthesis and Structural Characterization of Two Molybdenumphosphate Cluster Compounds: (C14N14H63) Na (H2Mo6P4O31)2 · 8H2O and (C14N14H63) Na (H2Mo6P4O31)2 · 5H2O[J]. Chinese Journal of Chemistry, 2002, 20(9): 858-864. DOI: 10.1002/cjoc.20020200911 |
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| Authors: | Fu‐Shan Wen Wei Chen Zhan Shi Guang‐Hua Li Zhen‐Tao Yu Jie‐Sheng Chen |
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| Abstract: | (C14N14H63) Na (H2Mo6P4O31)2 · 8H2O (1) with amine‐separated sodium molybdenumphosphate clusters and (C14N14H63) Na (H2Mo6P4O31)2 · 5H2O (2) with H‐bonded duster layers were synthesized from hydrothermal systems. Compound 1 crystallizes in the triclinic space group P · with a = 1.27445 (2) nm, b = 1.37183 (3) nm, c = 1.41515 (3) nm, α = 100.497 (1)°, β = 109.064 (1)° and γ = 115.498 (1)°. Whereas compound 2 has a monoclinic space group P21/n with a = 1.3418 (5) nm, b = 2.7787 (12) nm, c = 2.0314 (10) nm and β = 96.571 (14)°. There exist protonated ethylenediamine cations and H2O molecules between adjacent dusters, connecting the dusters through H‐bonds. |
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| Keywords: | molybdenumphosphate cluster crystal structure hydrothermal synthesis |
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