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The defect structure of ammonium sulphate single crystals
Authors:W J P Van Enckevort  H J Boeshaar  W H Van Der Linden  B Van Der Hoek
Abstract:The defect structure of larger ammonium sulphate crystals, grown from aqueous solutions, has been studied by means of X-ray diffraction topography after Lang's method. Several types of dislocations were identified. Moreover it was found that no relationship exists between growth rate and dislocation density, which implies that crystal growth proceeds via two-dimensional nucleation. No difference was found in the defect structure of crystals grown from pure water solutions and from aqueous solutions with 10 – 20% glycerine as additive: In both cases neither growth bands nor sector boundaries were found. On the other hand, crystals grown in aqueous solutions contaminated with Mn2+ and Fe3+ revealed growth bands and for Fe3+ a mosaic-like structure.
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