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Highly efficient synthesis of trimethylarsine
Authors:V. V. Gavrilenko  L. A. Chekulaeva  I. V. Pisareva
Affiliation:(1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation
Abstract:A convenient, highly efficient, and environmentally safe procedure for the preparation of trimethylarsine was proposed. A quantitative yield of this compound in the reaction of As2O3 with AIMe3 was attained for the first time by using mechanochemical activation of the process.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 2122–2123, August, 1996.
Keywords:trimethylarsine  trimethylaluminum  synthesis  ecological safety
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