Mössbauer and its r.f. sideband effects in iron-rich glassy alloys

Room temperature Mössbauer and its r.f. induced sideband effects are studied in glassy Fe₄₀Ni₄₀P₁₄B₆ and Fe₈₀P₁₆C₃B₁ alloys in ribbon forms. The direction of the magnetic anisotropy is found to be in the plane of the ribbon for the first alloy while the latter has some out-of-plane anisotropy component. The 3d electronic configuration for iron in the two alloys seems to be about the same in light of the observed isomer shifts and the electron donor model. The r.f. induced sidebands in the spectra are attributed to the magnetostriction of the present alloys.