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Configurational mixing and 4f-photoemission lineshapes in SmB6
Authors:J.-N. Chazalviel  M. Campagna  G.K. Wertheim  P.H. Schmidt
Affiliation:Bell Laboratories, Murray Hill, NJ 07974, U.S.A.
Abstract:Single crystal surfaces of the interconfiguration fluctuation material SmB6 have been studied by X-ray photoemission spectroscopy. Comparison with data for LaB6 allows a detailed analysis of the Sm 4f-spectrum. It yields a Sm2+/Sm3+ valence ratio of 0.4, a Coulomb correlation correlation energy oif 7 eV, and a 1 eV broadening of the Sm3+ 4f spectrum
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