New benzoxazine and benzothiazine dyes |
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Authors: | F. Chioccara G. Prota R.H. Thomson |
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Affiliation: | Istituto di Chimica Organica dell''Universita, via Mezzocannone 16, Naples, Italy;Department of Chemistry, University of Aberdeen, Meston Walk, Old Aberdeen, AB9 2UE, Scotland |
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Abstract: | 2H-1,4-benzoxazine can be generated in situ from 1-(o-aminophenoxy)-2,2′-dimethoxyethane in trifluoroacetic acid whence further reaction leads to the benzoxazine bye 7. The benzothiazine dye 9 can be derived in similar fashion from 1-(o-aminophenylthio)-2,2-diethoxyethane. |
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