High temperature degradation of compounds modelling polyimide fragments |
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Authors: | Yu.N. Sazanov L.A. Shibaev |
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Affiliation: | Institute of Macromolecular Compounds of the Academy of Sciences of the U.S.S.R. Leningrad U.S.S.R. |
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Abstract: | Chromatography and mass spectrometry were used to investigate products and kinetics of thermal, thermo-oxidative and thermo-hydrolytic degradation of compounds modelling fragments of polypyromellitdiphenyloxidediimide. Data on the degradation of benzoic and pyromellitic acids, diphenyl and diaminodiphenyl ethers, N-phenyl benzamide and N-phenyl phthalimide made it possible to draw conclusions concerning the effect of the chemical structure of polyimides on their thermal stability. |
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