Quelques aspects du mecanisme de l'oxydation anodique de quelques halogenures d'adamantyl-2 |
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Authors: | F. Vincent R. Tardivel P. Mison |
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Affiliation: | Laboratoire de Chimie Organique 3, Université Claude Bernard-Lyon 1, 43 Bd du 11 Novembre 1918, 69621 Villeurbanne, France |
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Abstract: | For the anodic oxidation in acetonitrile of some 2-adamantyl halides, the distribution of reaction products is dependent upon the halogen and substitution at the bridgehead positions. Iodides gave exclusively 2-adamantyl acetamides. 2-Chloroadamantane yields to chloroadamantyl acetamides. From bromides both 2-adamantyl acetamides and bromoadamantyl acetamides are formed. Part of the reaction products obtained with 2-fluoroadamantane are formed from the cleavage of C2F bond; this result is explained by analogy with the mass spectrometric fragmentation behavior of this compound. A general reaction mechanism covering all our experimental results is proposed. |
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Keywords: | Auteur à qui la correspondance doit-être adressée adresse actuelle: Institut de Chimie, Université de Constantine, route d'Aïn el Bey, Constantine, Algérie. |
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