A Mössbauer effect study of Dy impurities in the h.c.p. metal Zr

The 86.8 keV, 2⁺ → 0⁺ Mössbauer resonance of ¹⁶⁰Dy has been employed to study the paramagnetic hyperfine (hf) structure of Dy impurities in the hexagonal transition metal Zr. From the observed hf splitting it is concluded that the crystalline electric field ground state is an almost pure $\text{J}{}_{\mathrm{<mtext>z</mtext>}}\text{= ±}\text{1}\text{2}\text{Γ}{}_7$ Kramers' doublet with g_⊥ ? g_|. The quadrupole hf interaction and the effects of paramagnetic relaxation on the ME spectrum are also discussed.