Thermal rearrangement of 2-oxabicyclo[2.2.2]oct-5-eno-3-carboxylic acids |
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| Authors: | O Achmatowicz J Jurczak JS Pyrek |
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| Institution: | Institute of Organic Chemistry, Polish Academy of Sciences, 01-224 Warszawa, Poland |
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| Abstract: | The decarboxylation of 2-oxabicyclo2.2.2]oct-5-eno-3,3-dicarboxylic acid, obtained by hydrolysis of the Diels-Alder adduct of diethyl mesoxalate with cyclohexa-1,3-diene, gave two stereoisomeric γ-lactones of 2-hydroxy-1,2,5,6-tetrahydromandelic acid. |
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