首页 | 本学科首页   官方微博 | 高级检索  
     检索      


Chemisorption of carbon monoxide on platinum {111}: Reflection-absorption infrared spectroscopy
Authors:RA Shigeishi  David A King
Institution:The Donnan Laboratories, The University, Liverpool L69 3BX, England
Abstract:Reflection-adsorption infrared spectroscopy has been combined with thermal desorption and surface stoichiometry measurements to study the structure of CO chemisorbed on a {111}- oriented platinum ribbon under uhv conditions. Desorption spectra show a single peak at coverages > 1014 molecules cm?2, with the desorption energy decreasing with increasing coverage up to 0.4 of a monolayer, and then remaining constant at ≈135 kJ mol?1 until saturation. The “saturation” coverage at 300 K is 7 × 1014 molecules cm?2, and no new low temperatures state is formed after adsorption at 120 K. Infrared spectra show a single very intense, sharp band over the spectral range investigated (1500 to 2100 cm?1), which first appears at low coverages at 2065 cm?1 and shifts continuously with increasing coverage to 2101 cm?1 at 7 × 1014 molecules cm?2. The halfwidth of the band at 2101 cm?1 is 9.0 cm?1, independent of temperature and only slightly dependent on coverage. The band intensity does not increase uniformly with increasing coverage, and hysteresis is observed between adsorption and desorption sequences in the variation of both the band intensity and frequency as a function of coverage. The frequency shift and the virtual invariance of the absorption band halfwidt with increasing coverage (Jespite recent LEED evidence for overlayer compression in this system) are attributed to strong dipole-dipole coupling in the overlayer.
Keywords:
本文献已被 ScienceDirect 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号