Successive chemical solution deposition of ZnO films on flexible steel substrate: structure, photoluminescence and optical transitions

Zinc oxide is an attractive optoelectronic material with wide applications. Thin ZnO films were prepared on steel foil by successive chemical solution deposition (SCSD). The film structure, room-temperature photoluminescence (PL) and optical absorption characteristics were investigated. This study revealed that films of high structural and optical quality can be prepared by the SCSD method. PL of as-grown films shows a weak green peak at 560 nm and a strong UV peak at 380 nm. Annealing in either air or argon suppresses the green peak and red shifts the UV emission towards 390 nm. The presence of chlorine in the deposition solution destroys the PL of as-grown films. A strong UV emission, however, develops after annealing the films in air. Several optical transitions measured from the film PL and optical absorption coefficients are shown to be related to transitions through the known defect levels in ZnO, such as E₁, L₁, E₃ and V_O ²⁺ levels. PACS 81.16.Be; 81.05.Dz; 78.55.Et; 78.66.Hf; 68.55.Jk