| 有机-无机复合物[H2(PW12O40){Zn(C10H8N2)2(H2O)}]·1.5[Zn(C10H8N2)3]·1.75H2O的合成、结构及性能 |
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| 引用本文： | 叶燕珠,林深,陈心琴,徐伟. 有机-无机复合物[H2(PW12O40){Zn(C10H8N2)2(H2O)}]·1.5[Zn(C10H8N2)3]·1.75H2O的合成、结构及性能[J]. 无机化学学报, 2007, 23(2): 310-314 |
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| 作者姓名： | 叶燕珠 林深 陈心琴 徐伟 |
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| 作者单位： | 1. 福建师范大学化学与材料学院,福州,350007;福建教育学院化学与生命科学系,福州,350001
2. 福建师范大学化学与材料学院,福州,350007 |
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| 基金项目： | 福建省自然科学基金;福建省教育厅科研项目 |
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| 摘 要： | An organic-inorganic hybrid complex, [H2(PW12O40){Zn(C10H8N2)2(H2O)}]·1.5[Zn(C10H8N2)3]·1.75H2O has been synthesized hydrothermally and structurally characterized by X-ray crystallography. The crystal belongs to monoclinic, space grounp C2/c, with a=4.709 4(2) nm, b=1.431 77(7) nm, c=2.621 07(1) nm, β=90.125(4)°, V=17.673 4(2) nm3, Z=8, Dc=3.087 Mg·m-3, F(000)=14 884, μ(Mo Kα)=16.327 mm-1. The structure was refined to R1=0.068 7 and wR2=0.158 0 for 20 128 observed reflections with I>2σ(I). Single crystal structure shows that the title compound is constructed from [PW12O40]3- cluster anion and [Zn(C10H8N2)2(H2O)]2+ metal-organic complex cation, in which metal Zn(Ⅱ) cation are coordinately bonded to the terminal oxygen of Keggin polyanions. The title compound exhibits good catalytic activity for oxidation of benzaldehyde to benzoic acid. CCDC: 624772.
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| 关 键 词： | 多金属氧酸盐； 金属有机配合物； 锌； 水热合成 |
| 文章编号： | 1001-4861(2007)02-0310-05 |
| 修稿时间： | 2006-08-29 |
Synthesis, Crystal Structure and Catalytic Activity of an Organic-inorganic Hybrid Complex [H2(PW12O40){Zn(C10H8N2)2(H2O)}] · 1.5[Zn(C10H8N2)3]·1.75H2O |
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| YE Yan-Zhu,LIN Shen,CHEN Xin-Qin and XU Wei. Synthesis, Crystal Structure and Catalytic Activity of an Organic-inorganic Hybrid Complex [H2(PW12O40){Zn(C10H8N2)2(H2O)}] · 1.5[Zn(C10H8N2)3]·1.75H2O[J]. Chinese Journal of Inorganic Chemistry, 2007, 23(2): 310-314 |
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| Authors: | YE Yan-Zhu LIN Shen CHEN Xin-Qin XU Wei |
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| Affiliation: | College of Chemistry and Material Science, Fujian Normal University, Fuzhou 350007;Department of Chemistry and Life Science, Fujian Educational College, Fuzhou 350001,College of Chemistry and Material Science, Fujian Normal University, Fuzhou 350007,College of Chemistry and Material Science, Fujian Normal University, Fuzhou 350007 and College of Chemistry and Material Science, Fujian Normal University, Fuzhou 350007 |
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| Abstract: | |
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| Keywords: | polyoxometalate metal-organic complex zinc hydrothermal synthesis |
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