Role of monovalent alkali ions in the Yb3+ centers of CaF2 laser crystals |
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Authors: | Sana Hraiech Anis Jouini Kyoung Jin Kim Yannick Guyot Akira Yoshikawa Georges Boulon |
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Affiliation: | 1. Physical Chemistry of Luminescent Materials (LPCML), University of Lyon, Claude Bernard/Lyon 1 University, UMR 5620 CNRS, La Doua, 69622 Villeurbanne, France;2. IMRAM, Tohoku University, 2-1-1, Katahira, Sendai 980-8577, Japan |
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Abstract: | Yb3+ and M+ monovalent alkali ions (M+ = Li+, Na+, K+)-co-doped CaF2 cubic laser crystals were grown by the micro-pulling-down method (μ-PD) under CF4 atmosphere. Structural and spectroscopic characterizations of Yb3+ in substitution of Ca2+ (absorption, emission and decay curves) were carried out to study the effect of M+ ions as charge compensators. |
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