Ag (I)-based 2D metal frameworks with helical structures decorated by the homochiral camphor-10-sulfonic acid |
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| Authors: | Peng Guo Jing Wang Jun Wang Daocheng Pan Guohai Xu |
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| Institution: | 1. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, People’s Republic of China;2. Graduate School of the Chinese Academy of Science, Beijing 100049, People’s Republic of China;3. College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, PR China;4. Key Laboratory of Jiangxi University for Functional Materials Chemistry, Department of Chemistry and Life Science, Gannan Normal University, Ganzhou, Jiangxi 341000, People’s Republic of China |
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| Abstract: | Two two-dimension homochiral Ag (I) metal frameworks constructed from enantiopure camphor-10-sulfonic acid and hexamethylenetetramine have been synthesized at the room temperature. These two complexes with (6, 3) topology decorated by the homochiral camphor-10-sulfonic acid possess the unique helical structures. The result of Circular Dichroism (CD) spectroscopy confirms that the bulk materials are homochiral and also indicates the handedness of the single crystals can be controlled by the chirality of the camphor-10-sulfonic acid. |
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