Solvent-free sonochemical preparation of α-aminophosphonates catalyzed by 1-hexanesulphonic acid sodium salt |
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Authors: | Kirti S Niralwad Bapurao B Shingate Murlidhar S Shingare |
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Institution: | Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad 431 004, India |
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Abstract: | 1-Hexanesulphonic acid sodium salt was found to be an efficient catalyst for the green synthesis of α-aminophosphonates by the coupling of aldehydes/ketone, an amine and triethyl phosphite under ultrasound irradiation at ambient temperature for appropriate time to furnish the desired product in good to excellent yield under solvent-free condition. This catalyst provides clean conversion; greater selectivity and easy workup make this protocol practical and economically attractive. |
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