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Controlled methyl chloride synthesis at mild conditions using ultrasound irradiation
Authors:Maikel M van Iersel  Marcus A van Schilt  Nieck E Benes  Jos TF Keurentjes
Institution:1. Process Development Group, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands;2. AkzoNobel Industrial Chemicals, 3800 AE Amersfoort, The Netherlands;3. Membrane Technology Group, Faculty of Science and Technology, Institute of Mechanics, Processes and Control Twente (IMPACT), University of Twente, 7500 AE Enschede, The Netherlands
Abstract:A new route for the chlorination of methane is described using ultrasound irradiation, which allows for an intrinsically safe process at ambient pressure and temperature. By tuning the gas feed composition methyl chloride yields of up to 19% have been obtained.
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