| 苯丙氨酸桥联手性锌双卟啉受体对胺的分子识别 |
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| 引用本文： | 刘海洋,胡希明,应晓,刘义,黄剑,黄锦汪,计亮年,田瑄,杨立,朱启秀. 苯丙氨酸桥联手性锌双卟啉受体对胺的分子识别[J]. 高等学校化学学报, 1999, 20(6): 849-851 |
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| 作者姓名： | 刘海洋 胡希明 应晓 刘义 黄剑 黄锦汪 计亮年 田瑄 杨立 朱启秀 |
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| 作者单位： | 1. 华南理工大学应用化学系, 物理系, 广州 510640;2. 华南理工大学, 物理系, 广州 510640;3. 中山大学化学系, 广州 510275;4. 兰州大学应用有机化学国家重点实验室, 兰州 730000 |
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| 基金项目： | 国家自然科学基金,广东省自然科学基金,华南理工大学自然科学基金 |
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| 摘 要： | 金属卟啉的分子识别研究是当今卟啉仿生化学的重要课题.手性金属卟啉作为光学活性分子的对映选择识别受体和手性核磁共振试剂[1]尤为引人注目.
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| 关 键 词： | 苯丙氨酸 手性锌双卟啉 胺 分子识别 |
| 收稿时间： | 1998-07-21 |
Molecular Recognition of Amines by Phenylalanine Bridged Chiral Zinc Bis-porphyrin Receptor |
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| LIU Hai-Yang,HU Xi-Ming,YING Xiao,LIU Yi,HUANG Jian,HUANG Jin-Wang,JI Liang-Nian,TIAN Xuan,YANG Li,ZHU Qi-Xiu. Molecular Recognition of Amines by Phenylalanine Bridged Chiral Zinc Bis-porphyrin Receptor[J]. Chemical Research In Chinese Universities, 1999, 20(6): 849-851 |
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| Authors: | LIU Hai-Yang HU Xi-Ming YING Xiao LIU Yi HUANG Jian HUANG Jin-Wang JI Liang-Nian TIAN Xuan YANG Li ZHU Qi-Xiu |
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| Affiliation: | 1. Department of Applied Chemistry, South China University of Technology, Guangzhou, 510640;2. Department of Physics, South China University of Technology, Guangzhou, 510640;3. Department of Chemistry, Zhongshan University, Guangzhou, 510275;4. National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000 |
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| Abstract: | Interactions between amines and chiral zinc bisporphyrin linked with flexible alkyl chain containing phenylalanine () 1 were investigated by circular dichroism(CD) and UVVis spectroscopic titration method. CD and UVVis spectra of phenylalanine bridged chiral zinc bisporphyrin changes quite differently with the addition of propylamine and ethylenediamine in chloroform at room temperature. Our results indicate that phenylalanine bridged chiral zinc bisporphyrin is a potential CD probe of the functional group recognition for monoamine and diamine molecules as well as CD probe of the size specific recognition for ,diamines. |
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| Keywords: | Phenylalanine Chiral zinc bisporphyrin Amines Molecular recognition |
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