| 1，2-环己二胺缩邻香兰素单核与四核镱稀土配合物的近红外性质 |
| |
| 引用本文： | 范仲天,高博,董艳萍,邹晓艳,李光明.1，2-环己二胺缩邻香兰素单核与四核镱稀土配合物的近红外性质[J].无机化学学报,2013,29(18). |
| |
| 作者姓名： | 范仲天 高博 董艳萍 邹晓艳 李光明 |
| |
| 作者单位： | 黑龙江大学化学化工与材料学院, 功能无机材料化学省部共建教育部重点实验室, 哈尔滨 150080,黑龙江大学化学化工与材料学院, 功能无机材料化学省部共建教育部重点实验室, 哈尔滨 150080,黑龙江大学化学化工与材料学院, 功能无机材料化学省部共建教育部重点实验室, 哈尔滨 150080,《黑龙江大学工程学报》编辑部, 哈尔滨 150080,黑龙江大学化学化工与材料学院, 功能无机材料化学省部共建教育部重点实验室, 哈尔滨 150080 |
| |
| 基金项目： | 国家自然科学基金（No.51402092，21601132）资助项目。 |
| |
| 摘 要： | 通过配体1，2-环己二胺缩邻香兰素（H2L）和不同的镱盐反应，合成了4个镱稀土配合物Yb（H2L）2]（ClO4）3·2CH3OH·H2O（1），Yb4（L）4（NO3）2（H2O）2]（PF6）2·4CH3CN（2），Yb4（L）4（H2O）2Cl2]（PF6）2·2CH2Cl2·2H2O（3）和Yb4（L）4（NO3）2（H2O）2]Yb（NO3）3（H2O）2（CH3OH）]（NO3）2·4CH2Cl2·6CH3OH（4）。X射线单晶衍射分析表明配合物1为零维的单核结构，配合物2~4均为四核结构。研究了4个配合物的近红外发光性能。
|
| 关 键 词： | 近红外发光 镱配合物 结构 |
| 收稿时间： | 2017/5/18 0:00:00 |
| 修稿时间： | 2017/6/23 0:00:00 |
NIR Luminescent N,N'-Bis(3-methoxy-salicylidene)cyclohexane-1,2-diamine Mono-and Tetra-nuclear Ytterbium Complexes |
| |
| FAN Zhong-Tian,GAO Bo,DONG Yan-Ping,ZOU Xiao-Yan and LI Guang-Ming.NIR Luminescent N,N'-Bis(3-methoxy-salicylidene)cyclohexane-1,2-diamine Mono-and Tetra-nuclear Ytterbium Complexes[J].Chinese Journal of Inorganic Chemistry,2013,29(18). |
| |
| Authors: | FAN Zhong-Tian GAO Bo DONG Yan-Ping ZOU Xiao-Yan and LI Guang-Ming |
| |
| Institution: | Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistryand Materials Science, Heilongjiang University, Harbin 150080, China,Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistryand Materials Science, Heilongjiang University, Harbin 150080, China,Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistryand Materials Science, Heilongjiang University, Harbin 150080, China,Editorial Board of Journal of Engineering of Heilongjiang University, Harbin 150080, China and Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistryand Materials Science, Heilongjiang University, Harbin 150080, China |
| |
| Abstract: | A series of four N,N''-bis(3-methoxy-salicylidene)cyclohexane-1,2-diamine(H2L) ytterbium complexes, namely, Yb(H2L)2](ClO4)3·2CH3OH·H2O (1), Yb4(L)4(NO3)2(H2O)2](PF6)2·4CH3CN (2), Yb4(L)4(H2O)2Cl2](PF6)2·2CH2Cl2·2H2O (3) and Yb4(L)4(NO3)2(H2O)2]Yb(NO3)3(H2O)2(CH3OH)](NO3)2·4CH2Cl2·6CH3OH (4) have been isolated by reactions of H2L with various ytterbium salts and/or NH4PF6. X-ray crystallographic analysis reveals that complex 1 is of a discrete mononuclear structure, and complexes 2~4 are of homoleptic tetra-nuclears structure. The NIR luminescence of all complexes were investigated and discussed. CCDC: 916031, 1; 916032, 2; 916034, 3; 916033, 4. |
| |
| Keywords: | NIR luminescent ytterbium complexes structure |
|
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
