Synthesis of anti -[2.2] (2,6) benzothiazolophane: The first example of [2.2]benzofused heterophane |
| |
| Institution: | 1. State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China;2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China;1. Department of Biochemistry, Vanderbilt University School of Medicine, Nashville, TN 37232, USA;2. Department of Medicine (Hematology/Oncology), Vanderbilt University School of Medicine, Nashville, TN 37232, USA;3. VA Tennessee Valley Healthcare System, Nashville, TN 37212, USA;4. Department of Chemistry, Tennessee State University, Nashville, TN 37209-1561, USA;1. Department of Physics of Polymers and Crystals, Faculty of Physics, M.V. Lomonosov Moscow State University, Leninskie Gory 1, 119991, Moscow, Russia;2. A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Vavilova St. 28, INEOS, 119991, Moscow, Russia;1. Center for Advanced Studies in Chemistry, North-Eastern Hill University, Shillong 793 022, India;2. Department of Chemistry, University of Washington, Seattle, WA 98195, USA |
| |
| Abstract: | Synthesis of the first 2.2] benzofused heterophane 8 is described via photodecarboxylation of bislactone 7. Dynamic 1H NMR studies suggest that 8 is conformationally rigid whereas 7 is conformationally mobile on the NMR time scale. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
