Abstract: | We describe the facile preparation of novel, optically active nitridomanganese(V) complexes which serve as reagents for the electrophilic amination of sulfides. This amination method has several appealing features, including: i) the facile preparation of large quantities of the starting nitridomanganese reagent 3 , ii) the preparation of acylsulfilimines 2 in optically active form, and iii) the mild reaction conditions employed. |