A parametric analysis of the basic models of the mechanisms of the simplest catalytic reactions

A series of the simplest thermokinetic models, in which the kinetic subsystem corresponds to traditional catalytic mechanisms, such as the Eley-Rideal mono- and bimolecular mechanisms and the Langmuir-Hinshelwood mechanism, and autocatalytic mechanisms characterized by multiplicity of stationary states and autooscillations in the kinetic region, were considered. The method of continuation along a parameter was used for studying these basic models of thermokinetics. The parametric analysis performed allowed us to identify parameter regions characterized by critical effects (multiplicity of stationary states and autooscillations).