Synthesis and X-ray crystal structure studies of 1-ethyl-3-(2-chlorophenyl)-1,2,3-triazolium perchlorate |
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| Authors: | K Mantelingu KS Rangappa Basappa BH Doreswamy M Mahendra MA Sridhar J Shashidhara Prasad |
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| Institution: | (1) Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore, 570 006, India;(2) Department of Studies in Physics, University of Mysore, Manasagangotri, Mysore, 570 006, India |
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| Abstract: | The isolation of stable carbenes of the Arduengo (1a) and Wanzlick (2a) type has prompted us to look for stable nitrenium ions of the related structural type 1-ethyl-3-(2-chloropenyl)-1,2,3-triazolium perchlorate (6+ClO4
–). The title compound was synthesized and the structure was investigated by X-ray crystallography. It crystallizes in the monoclinic space group P2
1/n with cell parameters a = 7.066(4) Å, b = 27.680(6) Å, c = 7.486(2) Å,  = 111.22(3)°, and Z = 4. The structure exhibits arrangement of the molecules with intermolecular hydrogen bonds within the layers. |
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| Keywords: | Nitrenium ions carbenes triazolium perchlorates crystal structure |
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