Dipole-quadrupole and dipole-octopole polarizability of OsO4 from depolarized collision-induced light scattering experiments, ab initio and density functional theory calculations |
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Authors: | Hohm Uwe Maroulis G |
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Affiliation: | Institut für Physikalische und Theoretische Chemie der, Technischen Universit?t Braunschweig, Hans-Sommer-Strasse 10, D-38106 Braunschweig, Germany. u.hohm@tu-bs.de |
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Abstract: | The dipole-quadrupole and dipole-octopole polarizability of osmium tetroxide (OsO(4)) has been determined from collision-induced light-scattering experiments. Our final estimates for these properties are |A|=(84+/-5)e(2)a(3)(0)E(-1)(h) and |E|=(214+/-25)e(2)a(4)(0)E(-1)(h). We have also analyzed previous experimental data of the relative permittivity and refractivity of OsO(4) to propose the electronic part of the static dipole polarizability of alpha=51.0e(2)a(2)(0)E(-1)(h). To support our findings we have performed high-level ab initio and density functional theory calculations to obtain theoretical static estimates alpha=(50.2+/-1.6)e(2)a(2)(0)E(-1)(h), A=(84+/-10)e(2)a(3)(0)E(-1)(h), and E=(-252+/-32)e(2)a(4)(0)E(-1)(h), in essential agreement with the proposed experimental values. |
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