甲烷部分氧化制甲醛催化剂MoO_3/SiO_2及MoO-3·MxOy/SiO_2的程序升温还原研究 |
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引用本文: | 曹荣,陈燕馨,李峥嵘,李文钊. 甲烷部分氧化制甲醛催化剂MoO_3/SiO_2及MoO-3·MxOy/SiO_2的程序升温还原研究[J]. 分子催化, 1996, 0(5) |
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作者姓名: | 曹荣 陈燕馨 李峥嵘 李文钊 |
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作者单位: | 中国科学院大连化学物理研究所,中国科学院新疆化学研究所 |
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摘 要: | 利用程序升温还原(TPR)方法,研究了甲烷部分氧化制甲醛催化剂MoO3/SiO2及添加金属氧化物的MoO3·MxOy/SiO2(M=V、Fe、Ni、Cr、Cu)催化剂上,活性组分在载体上的分散及MoO3与MxOy的相互作用.发现钼含量的提高不利于MoO3在SiO2上的分散,催化剂表面晶相MoO3随钼含量的提高而增多.SiO2上担载的活性组分有一个最佳值,对应于最佳催化活性.MoO3·MxOy/SiO2催化剂中MoO3与MxOy发生了不同的相互作用,影响催化剂表面的活性氧物种,导致它们对甲烷氧化活性和甲醛选择性的不同.MoO3·V2O5/SiO2是比较好的催化剂,且V2O5添加量有最佳值,对应甲烷氧化制甲醛也有较高的活性和选择性.
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关 键 词: | 甲烷 部分氧化 MoO3/SiO2 MoO3·MxOy/SiO2 TPR 金属氧化物 |
TPR Study of MoO 3/SiO 2 and MoO 3 M xO y/SiO 2 Catalysts in Partial Oxidation of Methane |
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Abstract: | The technique of TPR (Temperature Programmed Reduction) has been used to investigate the diffusion of active components on silica and the interaction between MoO 3 and M xO y. Increasing of Mo content has great effect on the diffusion of MoO 3 on SiO 2 and the surface crystal MoO 3 on the catalysts increases with the increasing of Mo content. There is an optimum Mo content on silica which has the best catalytic activity. In MoO 3 M xO y/SiO 2 catalysts, different interaction exist between MoO 3 and M xO y which affects the surface active oxygen species of catalysts and leads to various methane oxidation activity and formaldehyde selectivity. MoO 3 V 2O 5 is found to be the much better catalyst and there is an optimum quantity of V 2O 5 added which gives rise to optimum interaction between MoO 3 and V 2O 5 and higher methane oxidation activity as well as formaldehyde selectivity. |
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Keywords: | Methane Partial oxidation MoO 3/SiO 2 MoO 3 M xO y/SiO 2 TPR Metal oxides Active oxygen species |
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