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Rate constant of capture of electron charge carriers on a screened repulsive center
Authors:A. V. Kalenskii  M. V. Anan’eva  V. G. Kriger  A. A. Zvekov
Affiliation:1. Kemerovo State University, Kemerovo, Russia
2. Institute of Coal Chemistry and Chemical Materials Science, Siberian Branch, Russian Academy of Sciences, Kemerovo, Russia
Abstract:The rate constant of capture of electron charge carriers on a screened repulsive center are performed. Approximate expressions for the potential barrier width, the capture cross section, and rate constant are derived. It is shown that the increase in the concentration of free charge carriers in silver azide from 1016 to 1020 cm?3 results in an increase in the capture rate constant by four orders of magnitude. It is also shown that, with increasing concentration of free carriers, the temperature dependence of the rate constant weakens and the effective activation energy of capture in silver azide decreases from 0.18 to 0.01 eV.
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