Benzindazoles from triketones of the indan series |
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Authors: | E Ya Ozola A K Aren G Ya Vanag |
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Institution: | (1) Institute of Organic Synthesis AS Latvian SSR, Riga |
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Abstract: | In the reaction of 2-acetonyl-and 2-phenacyl-2-phenylindan-1, 3-diones with hydrazine hydrate, the five-membered ring of the indandione system isomerizes into a six-membered ring forming derivatives of 5-hydroxy-1H-benzg]indazole. Derivatives of 3,4-(CO)-benzoylenepyridazine have been isolated as intermediates. The benzindazoles mentioned have been obtained by independent synthesis from the corresponding 2-acyl-1, 4-dihydroxynaphthalenes.For part I, see 1]. |
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