Synthesis of Dioxa-Cages as a New Probe for the Stereochemistry of the Bisadducts of p-Quinone with Cyclopentadiene and Cyclohexadiene |
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Authors: | Chia-Hui Yen Shih-Hwa Tsai Hsien-Jen Wu |
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Abstract: | The synthesis of dioxa-cages via iodine-induced cyclization reaction can be used as a new method for the determination of the stereochemistry of the bisadducts of p-quinone with cyclopentadiene and cyclohexadiene. The bisadducts 2 and 8 were converted into the dioxa-cages 13a and 13b via a three-step sequence, respectively. The stereochemistry of 13a and 13b was determined on the basis of NOE experiments. |
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Keywords: | Synthesis of dioxa-cages Bisadducts of p-quinone with cyclopentadiene and cyclohexadiene |
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