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Tandem Thermal Reactions for the Synthesis of Jasmonoids |
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| Authors: | Tse-Lok Ho Kuo-Feng Shyu |
| Abstract: | A tandem reaction tactic for the preparation of a jasmonoid intermediate consists of pyrolysis of a spiroannulated cyclopentanone. The thermal decomposition actually involves a retro-Diels-Alder reaction and a homo-1,5-hydrogen shift with cleavage of the cyclopropane unit. |
| Keywords: | Tandem reaction Pyrolysis Jasmonoid |