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Alkoxide-Accelerated [1,3] Sigmatropic Shift of Bicyclo[3.2.1]oct-6-en-2-ols to 8-endo-Hydroxybicyclo[3.3.0]oct-2-en-4-ones |
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| Authors: | Yeh-Long Chen Chi-Kang Chang Nein-Chen Chang |
| Abstract: | Bicyclo[3.2.1]oct-6-en-2-ols 6 are shown to undergo [1,3] sigmatropic shift to afford 8-endo-hydroxy-bicyclo[3.3.0]oct-2-en-4-ones 8 under the influence of potassium hydride. |
| Keywords: | Bicyclo[3.3.0]octenes Alkoxide-accelerated [1,3] sigmatropic shift Bicyclo[3.2.1]octenols |