| 分子印迹聚合物固相萃取红椒粉中的苏丹红Ⅰ |
| |
| 引用本文： | 徐莉,刘英菊,刘有芹,刘岚.分子印迹聚合物固相萃取红椒粉中的苏丹红Ⅰ[J].化学研究与应用,2008,20(7). |
| |
| 作者姓名： | 徐莉 刘英菊 刘有芹 刘岚 |
| |
| 作者单位： | 1. 华南农业大学化学系,广东,广州,510642
2. 中山大学化学与化学工程学院,广东,广州,510275 |
| |
| 基金项目： | 国家自然科学基金项目
,
华南农业大学校长基金项目 |
| |
| 摘 要： | 本文以苏丹红Ⅰ为模板分子,以甲基丙烯酸(MAA)、4-乙烯基吡啶(4-VPy)为功能单体,制备了两种模板聚合物(MAA-MIP和4-VPy-MIP)。对4-VPy-MIP进行了Scatchard方程分析。分别以这两种模板聚合物为固相萃取材料来填充固相萃取柱,从掺有苏丹红Ⅰ的红椒粉中萃取苏丹红Ⅰ。本文优化了固相萃取条件。高效液相色谱检测表明,在合适的萃取条件下,采用填充4-VPy-MIP的固相萃取柱可以有效地从红椒粉中分离富集苏丹红Ⅰ。
|
| 关 键 词： | 分子印迹聚合物 固相萃取 苏丹红Ⅰ 高效液相色谱 |
Molecularly imprinted solid phase extraction for detection of sudan I in red peppers |
| |
| XU Li,LIU Ying-ju,LIU You-Qin,LIU Lan.Molecularly imprinted solid phase extraction for detection of sudan I in red peppers[J].Chemical Research and Application,2008,20(7). |
| |
| Authors: | XU Li LIU Ying-ju LIU You-Qin LIU Lan |
| |
| Institution: | XU Li1,LIU Ying-ju1,LIU You-Qin 1,LIU Lan2 |
| |
| Abstract: | In this paper,two kinds of molecularly imprinted polymers(MIPs) were prepared with different functional monomers as methacrylic acid(MAA) and 4-vinylpyridine(4-VPy).The polymeric material was characterized by scanning electronic microscope and Scatchard analysis.The polymeric particles were packed into 6cm glass columns to be invested to absorb selectively Sudan I from red peppers.Under the extraction conditions,the high performance liquid chromatography(HPLC) indicated the MISPE packed with 4-Vpy-MIP possessed excellent selectivity toward the template comparing the MAA-MIP. |
| |
| Keywords: | molecularly imprinted polymer solid phase extraction sudan I high performance liquid chromatography |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
