| Tin Oxide and Carbon Composite （Sn6O4（OH）4/AG） as the Anode in a Lithium Ion Battery |
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| 引用本文： | 林克芝,王晓琳.Tin Oxide and Carbon Composite （Sn6O4（OH）4/AG） as the Anode in a Lithium Ion Battery[J].清华大学学报,2005,10(5):554-560. |
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| 作者姓名： | 林克芝 王晓琳 |
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| 作者单位： | Department of Chemical Engineering, Tsinghua University, Beijing 100084, China |
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| 摘 要： | A tin oxide and carbon composite （Sn6O4（OH）4/AG） with a Sn content of 0.15-0.30 was prepared by chemical deposition at normal pressures and temperatures. The structures of the artificial graphite （AG）, the Sn6O4（OH）4, and the Sn6O4（OH）4JAG were analyzed using X-ray diffraction. The electrochemical lithiation was investigated by measuring the galvanostatic charge and discharge ratio. The electrochemical capacities of the three materials during the first discharge were 310 mAh/g （AG）, 616 mAh/g （Sn6O4（OH）4/AG）, and 1090 mAh/g （Sn6O4（oa）4）. The discharge capacity of the Sn6O4（OH）4/AG was larger than the simple sum of the capacities provided by AG and Sn6O4（OH）4 with the same content. The cyclic performance of Sn6O4（OH）4/AG was also better than that of Sn6O4（OH）4 for voltages of 0 to 3 V. The results imply that the interaction between Sn and C in Sn6O4（OH）4/AG is very strong and effectively inhibits the volume expansion of the Sn.
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| 关 键 词： | 锂离子电池 电解液 阳极材料 人造石墨 氧化锡 |
| 收稿时间： | 2004-10-16 |
| 修稿时间： | 2004-10-16 |
Tin Oxide and Carbon Composite (Sn6O4(OH)4 /AG) as the Anode in a Lithium Ion Battery |
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| Kezhi Lin, &#x;
,Xiaolin Wang, &#x;&#x;.Tin Oxide and Carbon Composite (Sn6O4(OH)4 /AG) as the Anode in a Lithium Ion Battery[J].Tsinghua Science and Technology,2005,10(5):554-560. |
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| Authors: | Kezhi Lin &#x;
Xiaolin Wang &#x;&#x; |
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| Institution: | Department of Chemical Engineering, Tsinghua University, Beijing 100084, China |
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| Abstract: | A tin oxide and carbon composite (Sn6O4(OH)4/AG) with a Sn content of 0.15-0.30 was prepared by chemical deposition at normal pressures and temperatures. The structures of the artificial graphite (AG), the Sn6O4(OH)4, and the Sn6O4(OH)4/AG were analyzed using X-ray diffraction. The electrochemical lithiation was investigated by measuring the galvanostatic charge and discharge ratio. The electrochemical capacities of the three materials during the first discharge were 310 mAh/g (AG), 616 mAh/g (Sn6O4(OH)4/AG), and 1090 mAh/g (Sn6O4(OH)4). The discharge capacity of the Sn6O4(OH)4/AG was larger than the simple sum of the capacities provided by AG and Sn6O4(OH)4 with the same content. The cyclic performance of Sn6O4(OH)4/AG was also better than that of Sn6O4(OH)4 for voltages of 0 to 3 V. The results imply that the interaction between Sn and C in Sn6O4(OH)4/AG is very strong and effectively inhibits the volume expansion of the Sn. |
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| Keywords: | electrochemical lithiation artificial graphite Sn-based material |
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