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Far infrared emission spectra from stratospheric hydrogen peroxide
Authors:B Rebours
Institution:(1) Laboratoire de Géophysique Externe, D.P.A.M. URA 1203, Université de Rennes I, B.P. 150, 22302 Lannion, France
Abstract:Synthetic emission spectra from two stratospheric altitude observations have been analyzed for the presence of H2O2 in the far infrared region. The calculations are made with a high spectral resolution (10–3 cm–1 or 10–4 cm–1) greater than those in experimental measurements which are in the region of 3.10–3 cm–1. Spectra cover a spectral interval between 40 and 120 cm–1 showing the best features of H2O2 susceptible to observation in a stratospheric spectrum. The optimum conditions for identification have been considered. Using the variations in H2O2 abundance in the measurement data and photochemical models, the H2O2 features detection limits have been studied.
Keywords:far-infrared  stratospheric emission  minor constituents
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